GIMP tutorial showing the true power of paths, layers and layer masks. This tutorial involves using the paths tool to create a selection for making a layer mask to cut an image from it's background, and apply a new background. Basically a photo collage, or photomanipulation.
If you want the image files to try out this tutorial out for yourself, here they are:
http://oi39.tinypic.com/rtgodf.jpg
http://oi43.tinypic.com/9ibgwm.jpg